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Indexed values are sorted lexicographically, but sorting is not applied until you request it by using one of the appropriate methods:
To get ordered results we need to indicate a field name to sort by:
List<FileHeader> results = await session.Query() .OrderBy(x => x.Name) .ToListAsync();
You can also retrieve results in descending order:
List<FileHeader> results = await session.Query() .OrderByDescending("Owner") // order descending by "Owner" metadata .ToListAsync();